1. Topic

  How to reduce industries emissions in urban areas

2. Introduction

   

Industrial sources in or close to urban areas can be major sources of VOCs (Volatile Organic Compounds) when solvents are employed during the production cycle. This Topic description focuses on the reduction of VOCs. The very wide chemical class of VOCs includes some toxic and/or carcinogenic compounds as the 1,3-butadiene, the PAHs (Polycyclic Organic Hydrocarbons), the dioxins and many others. Furthermore, once in the atmosphere, VOCs play a major role in the formation of the ozone and the secondary organic fraction of the particulate matter.

The SNAP 97 classification lists the main activities involving solvent use: paint application (0601), degreasing, dry cleaning and electronics (0602), chemical products manufacturing or processing (0603) and other use of solvents (0604 – including wood preservation, glass wool production, printing industry and others).

The main legislative instrument for EU Member States in dealing with solvent related emissions is the directive 1999/13/EC (the so-called VOC and solvent directive) but other directives involving air quality and IPPC (Integrated Pollution Prevention and Control) are also relevant.

3. Discussion

   

The “Solvent Directive” 1999/13/EC

The Solvent Directive identifies a group of industrial activities involving a non negligible use of solvents (Annex I) and sets limits on solvent emissions in the air taking into account both fugitive emissions and emissions in waste gases. These limits are required for all new installations whereas all existing installations must comply with the limits by 31 October 2007 at the latest.

Besides the emission limits compliance (the so-called “end of pipe” approach), the Directive offers another pathway to emission reductions based on a “reduction scheme”. Annex IIB states that “the purpose of the reduction scheme is to allow the operator the possibility to achieve by other means emission reductions, equivalent to those achieved if the emission limit values were to be applied”. Equivalent reductions can be achieved by means of decreases in the average solvent content of the total input and/or increased efficiency in the use of solids. In the case of industrial installations operating in applying coatings, varnishes, adhesives or inks the directive sets the scheme of the mass balance to be employed to demonstrate the actual equivalent reduction. In this approach authorized emissions are estimated on the basis of the solid coating used by means of a factor taking into account the industrial activity of the installation and, in some cases, the installation size.

For a group of solvents classified as carcinogenic, mutagenic or toxic for the reproduction stricter rules are set and the substitution with less dangerous compounds is required as soon as technically feasible.

“End of pipe” and reduction scheme approaches

The freedom of choice between the two approaches to the solvent emissions reduction is probably the most interesting point of the Directive. Industrial operators are expected to consider the two approaches, to draft a cost-benefit study and definitively to choose the most appropriate path to solvent reduction.

The “end of pipe” approach can be realized through a number of technical measures including (list from abatement tutor and a sentence on the tutorial). Many public (UNECE, 2000) and private bodies (ESIG, 2002) have produced detailed benchmarking and tutorial tools to help the industrial operators to select the most appropriate and cost-effective Best Available Techniques (BAT), (as defined in the IPPC Directive 61/96/EC) for VOC abatement. Especially SMEs or local SMEs associations are expected to use these tools.

The “end of pipe” approach to the VOC emissions control does not imply any change in the production cycle. It obtains a downstream impact reduction, but does not necessarily induce a reduction of the overall amount of solvents involved in the production cycle and/or contained in the final product.

On the contrary, the reduction scheme approach requires an integrated tuning of the production cycle. A number of case studies (Envirowise, 2001) shows as reduction can be achieved for example by means of solvent adsorption and recovery systems (Entek International) or efficient paint spray guns (ABT Products).

In the case of some industries (coating and painting industries) the reduction scheme approach can be easily applied by switching to materials containing a smaller percentage of solvents. Also in these cases, extensive “good practice guidelines” have been developed to assist industrial operators in setting up reduction schemes and solvent management plans (Information Exchange Network, 2001).

Future developments: the “Decopaint” Directive

Minimising the amount of solvents in the coating products is coherent with the “reduction scheme” approach and produces the important side advantage of decreasing the overall amount of solvent pollutants in the environment. Furthermore, limiting the amount of solvents in a number of products is expected to lead to important benefits also when non-industrial sources are involved as in the case of domestic indoor air pollution.

The feasibility of a legislative approach based on solvent content of products depends on the availability and cost of effective substitutes of the products employed now.

Feasibility studies have commissioned by DG Environment have shown as decorative paints and varnishes and vehicle refinishing activities can count on a set of less harmful products and the substitution could lead to sensible benefits for the environment.

The Decopaint Directive is in the final part of its legislative path as the European Parliament has approved the second reading without amendments. The Directive will fix stringent limits on the content of VOC for a number of product categories following a two-stage approach with two successive deadlines at 1/1/2007 and 1/1/2010.

Other relevant legislative tools

Solvent emission is considered in the “national emission ceilings” directive 2001/81/EC setting an overall emission limit for Member States. Furthermore, VOCs emissions have to be controlled and limited in the critical area for ozone as they act as precursors. The “Ozone daughter directive” 2002/3/EC names 31 VOCs as ozone precursors that should be measured in the ambient air in order to check the effectiveness of reduction strategies.

Finally, all measures involving industrial plants relevant for the IPPC Directive (96/61/EC) have to fulfil its requirements.

4. Recommendation / Conclusion

   

Above, the legal framework for controlling VOC emissions is described. In addition to activities to control these emissions, cities are advised to allocate polluting activities as far as possible from populated areas. The VOC emissions deriving from such activities can be negative for ozone formation, so an overall “budget” could be drafted by the Regional Authority or from the Authority releasing the permit.

5. Examples / Further Reading

   

A rich example on ways to reduce the emissions from industrial sites in the Venice area is given in Example Programme agreements tools to reduce pollutant emissions from industrial sites in municipal Venice.


Further Examples:

Environmental improvement resulting from oxycombustion technology
Air Quality Management and Available Economic Resources

6. Additional Documents / Web Links

   

· Solvent emission legislation: http://europa.eu.int/comm/environment/air/stationary.htm#3

· Solvent Directive 1999/13/EC: OJ L85, 29/03/1999, 1-22

· Information exchange network the EU Solvent Directive: http://www.voc-infoex.uni-karlsruhe.de/

· UNECE, 2000: guidance document on control techniques for emissions of VOCs from stationary sources: http://www.unece.org/env/lrtap/protocol/guid_docs/guid_ch3.htm

· ESIG (European Solvents Industry Group), 1999: Abatement advisor – freely available at http://www.esig.org/pub.htm

· DG Environment (tender), 2000. Study on the Potential for Reducing Emissions of Volatile Organic Compounds (VOC) Due To The Use Of Decorative Paints and Varnishes for Professional and Non-professional Use. http://europa.eu.int/comm/environment/air/background.htm#stationary.

· Envirowise, 2001. Solvent and VOC cost savings: http://www.envirowise.gov.uk/envirowisev3.nsf/key/KBRL5F5NZ

Last Updated


 

25th January 2005

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